Chloromethylated Polystyrene (Ps––Ch2cl) Reacts With 3-Formylsalicylic Acid and Forms Polystyrene 3-Formylsalicylate. the Nucleophilic Addition Reaction Followed By the Elimination of One Water Molecule Between Polystyrene-3-Formylsalicylate and O-Hydroxyphenylurea In Dmf In the Presence of Ethyl Acetate Results In the Formation of Polystyrene-Anchored Schiff Base, Psch2––Lh3 (19). the Polystyrene-Anchored Coordination Compounds of the Types, [Psch2––Lh2cu(Oac)(Dmf)] (20), [Psch2––Lh2cd(Oac)(Dmf)] (21), [Psch2––Lh2mn(Oac)(Dmf)3] (22), [Psch2––Lh2fecl2(Dmf)2] (23) and [Psch2––Lh2moo2(Acac)] (24) (Acach = Pentane-2,4-Dione) Have Been Synthesized By Refluxing a Dmf Swollen Suspension of 19 and Appropriate Metal Saltscompound. the Polystyrene-Anchored Coordination Compounds Have Been Characterized on the Basis of Elemental Analyses, Spectral (Ir, Reflactance, Esr) and Magnetic Susceptibility Measurements. 19 Behaves As a Monobasic Bidentate on Donor Ligand In These Coordination Compounds. [Psch2––Lh2cu(Oac)(Dmf)] (20) Is Square-Planar and Paramagnetic, [Psch2––Lh2cd(Oac)(Dmf)] (21) Is Tetrahedral and Diamagnetic. the Paramagnetic Compounds (22 and 23) and the Diamagnetic Compound (24) Have Attained an Octahedral Geometry.